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Ligand-free Copper-catalyzed Cascade Reactions of 2-Halo-amides with o-Halophenols and 2-Bromobenzenethiol: We have developed a simple and efficient ligand-free and copper-catalyzed method for the synthesis of2H-1,4-be...; Fan,LiyuanWu,SanHu,WeiyeZhang,Songlin; 关键词：LIGAND-FREE COPPER-CATALYZED HETEROCYCLE

A Facile One-pot Synthesis of a-Halo,a-allylic Aldehydes from a,a-Dihalo Ketones Utilizing Allylic Zinc Bromide: 2012年; An efficient synthesis of various a-halo,a-allylic aldehydes from a,a-dihalo ketones using both cyclic （3-bromocyclohex-1-ene zinc bromide and （Z）-3-bromocyelobut-l-ene zinc bromide） and acyclic （allylzinc bromide and cinnamylzinc bromide） type of allylic organozinc bromide with DMF as base is described. A possible reaction mechanism is also proposed.; 王晓磊张松林; 关键词：ALDEHYDE ALLYLATION

铁铜催化下唑类化合物与芳基硼酸的直接芳基化反应: 论文研究了一种环保高效的合成芳基取代的唑类化合物的新方法,本研究以廉价无毒的铁铜为催化剂活化唑类化合物的C-H键和芳基硼酸的C-B键实现唑类化合物和芳基硼酸的直接偶联。这种方法可以以较好的收率适用于一系列官能团化芳基硼酸...; 胡伟业郑松林张松林; 关键词：唑类化合物

Iron and Copper Catalyzed C-H Arylation of Azoles with Aryl Boronic Acids: Heterocyclic compounds are always found with specific function for their peculiar structures.Some heterocyclic...; 胡伟业王培培张松林; 关键词：IRON COPPER AZOLE ARYL

Di-Applications of Allylsamarium Bromide as Grignard Reagent and a Single Electron Transfer Reagent in the One-pot Synthesis of Terminal Olefins: The utility of allylsamarium bromide,both as a nucleophilic reagent and a single-electron transfer reagent in ...; Li,YingHu,YuanYuanZhang,SongLin; 关键词：BROMIDE ONE-POT TERMINAL OLEFIN

Barbier Reaction and Olefination Reaction of Ketones Promoted by Neodymium: Neodymium metal in the presence of catalytic amounts of iodine was found to be effective for the Barbier react...; Wang,PeieiWang,RuZhang,Songlin; 关键词：NEODYMIUM REACTION OLEFINATION REACTION

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国家自然科学基金(21072143)