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国家自然科学基金(ZJNSF)

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High-performance supercapacitors based on free-standing SiC@PEDOT nanowires with robust cycling stability被引量:2
2022年
Conductive polymers as one of the candidate materials with pseudocapacitor behavior have inspired wide attentions,because of their high conductivity,fexibility,low cost and excellent processability.However,the intrinsically poor cycling stability induced by the volume change over the doping/dedoping redox process limits their practical applications.Herein,we report the exploration of electrodes with robust cycling capacity for supercapacitors(SCs),which are rationally designed by coating conductive poly(3,4-ethylenedioxythiophene)(PEDOT)around free-standing SiC nanowires using an all-dry oxidative chemical vaper deposition(oCVD)method.The as-constructed SiC@PEDOT nanowire architecture enables a specific capacitance of 26.53 m F/cm^(2)at 0.2 m A/cm^(2),which is~370%to that of SiC nanowire counterpart(7.04 m F/cm^(2)).Moreover,their aqueous-based SCs exhibit robust cycling stability with104%capacity retention after 10000 cycles,which is among the highest values achieved for PEDOTbased SCs.
Wenna LiuXiaoxiao LiWeijun LiYumin YeHong WangPeipei SuWeiyou YangYa Yang
关键词:SUPERCAPACITOR
Numerical prediction of indoor airborne particle concentration in a test chamber with drift-flux model
2011年
The time-dependent variation of airborne particle concentration for different sizes in a test chamber was numerically predicted with drift-flux model. The performance of the drift-flux model for particle transport in different kinds of airflow fields was analyzed. The results show the drift-flux model can predict the transport of indoor fine particles reasonably well. When the air flow field varies slowly, the model can predict both the time-dependent variation ratio of the particle concentration and final stable concentration very well, and the difference for particles with different sizes can be also well predicted. When the air flow varies drastically, the accuracy of the model is decreased due to the neglect of the particles’ independent convective terms in the air flow.
Hanhui JinYong ChenQinping LiJianren FanKun Luo
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